Samba Unable to create new folder in accessed share

If there is no content in the folder - there is no mounted device.

Dolphin uses some behind the scenes - not directly accessible - kde logic.

There is no KDE equivalent to gio mount which may be a possible explanation to why dolphin has issues.

If you use the mount utility from this topic you will get a folder named SMBLinks in home which holds a symlink to real mount location.