The following worked for me:
Put the following in ~/.config/gtk-3.0/settings.ini (create the file if it doesn’t exist):
[Settings]
gtk-recent-files-max-age=0
gtk-recent-files-limit=0
Then, remove the file holding recently-used data:
rm ~/.local/share/recently-used.xbel
The recently-used.xbel file got recreated after deletion with this content:
<?xml version="1.0" encoding="UTF-8"?>
<xbel version="1.0"
xmlns:bookmark="http://www.freedesktop.org/standards/desktop-bookmarks"
xmlns:mime="http://www.freedesktop.org/standards/shared-mime-info"
></xbel>