Keyboard Shortcuts Not Persistent in Plasma 6

Thats your problem then.
You are correct khotkeys is deprecated. Even if you previously used it for shortcuts, you would need to remove it and apply them again using kglobalaccel.
I dont know how you are missing kglobalaccel, as its part of plasma.

sudo pacman -Rns khotkeys
sudo pacman -Syu plasma-desktop

As mentioned, kglobalaccel is a dependency of plasma-desktop.
Your shortcuts should be configurable through System Settings as usual.
And/or directly by kglobalaccel.

PS

Your missing core packages makes me wonder about the general integrity of your system.
Have you accidentally removed things?
Performed a partial-upgrade?

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