It looks to me, that you changed “alot”… maybe to much?
Can you remember when firefox the first time has problems? Maybe a Addon that causes this problems?
Possible a problem with xfce… who knows. Im using Manjaro KDE with 5.15 LTSC and adjusted with alot custom settings. And no issue at all, since above 2 years Manjaro time.
Edit:
But i also had a VA-API error in Firefox that caused errors in Journal, few month ago… but firefox was still working fine, even with that error messages: