Reclaim a keyboard shortcut

I use an application that has the keyboard shortcut Alt-F7. But xfce is getting it first. I can see it defined in this file: ~/.config/xfce4/xfconf/xfce-perchannel-xml/xfce4-keyboard-shortcuts.xml. Am I just supposed to comment it out there and reboot my machine? I can only see a handful of shortcuts in the UI application ‘Keyboard’, certainly not Alt-F7. What’s the official way to reclaim a keyboard shortcut?

Some shortcuts are related to the window manager.

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