A Duplex audio profile is for audio playback and capture
Analog Stereo Duplex = analog-stereo-output + analog-stereo-input
Archwiki - mpv - Specify an audio output
Run the following command to get a list of available audio output devices
mpv --audio-device=help
Then add one to ~/.config/mpv/mpv.conf. For example:
audio-device=alsa/hdmi:CARD=NVidia,DEV=1
but you would probably want to select a pulse or pipewire output rather than alsa, so it does not take exclusive control of audio playback device, or fail to play audio if device is already connected to PulseAudio or PipeWire