How can I have two user graphical sessions open at the same time and switch between them using a shortcut similar to how I can switch workspaces?

If switching between two sessions is what you are looking for, you can find it in the top right applet called “User Applet”, there you will find the *SwitchUser* menu item to allow you to quickly switch between two or more users.

If it is not there, just right click on the top bar and click Applets, you can add it from there.

John