Cannot boot with 20-amdgpu.conf present in /etc/X11/xorg.conf.d/

Should be like this according to AMDGPU - ArchWiki :

Section "OutputClass"
     Identifier "AMD"
     MatchDriver "amdgpu"
     Driver "amdgpu"
     Option "TearFree" "true"
     Option "VariableRefresh" "true"
     Option "AsyncFlipSecondaries" "true" #multimonitor setup, but at least one is not FreeSync capable
EndSection

But, do you have a monitor that is in this list https://www.amd.com/en/products/freesync-monitors
What kernel are you using?